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朱钢国

发布日期 :2022-02-23    阅读次数 :19597

课题组合影


钢国博士,教授,省“万人计划”科技创新领军人才,Tel0579-82282640E-mail: gangguo@zjnu.cn主要经历如下

19969月-20007月:浙江师范大学化学系,理学学士。2000920057月:中科院上海有机化学研究所理学博士,导师张兆国教授。20059200710月:普渡大学诺贝尔化学奖得主Negishi教授课题组博士后研究200711200810月:印第安纳大学博士后研究。200812至今:浙江师范大学。现为教授、博、化学与生命科学学院院长、浙江省化学会常务理事,2013年入选浙江省高校中青年学科带头人,2016年入选浙江省151人才工程第二层次培养对象、校首批“双龙学者”特聘教授,2020年入选省高校中青年领军人才、浙江省“万人计划”科技创新领军人才。独立工作后,发表Angew. Chem. Int. Ed.Nat. Commun.Chem. Sci.Org. Lett.Chem. Commun.SCI论文70篇,授权发明专利10余件,先后主持国家自然科学基金4项、浙江省自然科学基金杰出青年项目、重点项目等省部级项目5项,完成企业横向项目3项,主要从事自由基反应、过渡金属催化的氟化反应和生理活性的天然产物合成研究

获奖:

1. 2019 Thieme Chemistry Journal Award

2. 2015年浙江省自然科学奖三等奖:杂原子取代炔烃的亲核金属化反应方法学研究(第一完成人)。

32012年度浙江省高校优秀科研成果奖一等奖:杂原子取代炔烃的亲核钯化反应方法学研究(第一完成人)。

主持项目:

1. 国家自然科学基金面上项目:自由基加成启动的非末端炔烃远程碳-氢键官能团化反应研究(22071218)

2. 浙江省自然科学基金重点项目:杂原子取代炔烃自由基加成启动的远程sp3-氢键官能团化反应研究(LZ20B020002)

3. 国家自然科学基金面上项目:过渡金属催化的醛直接转化为酮的自由基反应研究(21672191),已结题;

4. 浙江省公益性技术应用研究计划项目:2-氨基呋喃化学品的催化合成技术研究(2015C31030),已结题;

5. 国家自然科学基金面上项目:基于1,2-双官能团化烯烃的偶联反应选择性合成多取代烯烃(21172199),已结题;

6. 浙江省杰出青年基金:1--1-硫代烯烃的立体选择性合成及其三取代烯烃的构建(LR12B02001),已结题;

7. 国家自然科学基金青年基金:偶极烯丙基钯的环加成反应研究(20902084),已结题;

8. 浙江省钱江人才计划项目:抗禽流感药物达菲的合成工艺研究(2010R10016),已结题。

发表文章

2022

1. [3+2] Cycloaddition of alkyl aldehydes and alkynes enabled by photoinduced hydrogen atom transfer, Le, S.; Li, J.; Feng, J.; Zhang, Z.; Bai,Y.; Yuan Z.; Zhu, G.*Nat. Commun. 2022, 13, 4734.

2. Photocatalytic Sulfonylcarbocyclization of Alkynes Using SEt as a Traceless Directing Group: Access to Cyclopentenes and Indenes, Zhou, Y.; Qin, Y.; Wang, Q.; Zhang, Z.; Zhu, G.* Angew. Chem. Int. Ed.2022,61, e202110864. Highlighted by https://www.x-mol.com/news/733556.

3. A diastereoselective synthesis of cyclopentanones via photocatalytic reductive alkyltrifluoromethylation of ynones,Qiu, J.;Le, S.; Su, J.; Liu, Y.; Zhou, Y.; Zheng, H.; Bai, Y.; Zhu, G.*Org. Chem. Front.2022, DOI:10.1039/D2QO01101H.

4. Access to cyclopentenones via copper-catalyzed 5-endotrifluoromethylcarbocyclization of ynones, Le,S.; Bai,Y.; Qiu,J.; Zhang,Z.; Zheng,H.* Zhu, G.*Org. Chem. Front.2022, 9, 4670-4675.

5. Copper-Catalyzed 1,2,5-Trifunctionalization of Terminal Alkynes Using SR as a Transient Directing Group for Radical Translocation, Feng,J.; Zhang, F.; Shu, C.;Zhu, G.*Chin. J. Chem.2022, 40,1667-1673. 

2021

6. Solvent-controlled photocatalytic divergent cyclization of alkynyl aldehydes: access tocyclopentenones and dihydropyranols, Zhu, H.; Zheng,H.; Zhang, J.; Feng, J.; Kong, L.; Zhang, F.; Xue, X.-S.;* Zhu, G.* Chem. Sci. 2021, 12, 11420-11426.

7. Radical Chain Isomerization of N-Sulfonyl Ynamides to Ketenimines and Its Application to Furan Dearomatization, Shen, J.; Wu, Z.; Liu, Y.; Bai, Y.; Qiu, J.; Zhang, Z.; Yuan, Z.;*Zhu, G.* Org. Lett. 2021, 23, 9321-9326.

8. Synthesis of polysubstituted azetidines via cascade trifluoromethylation/cyclization of N-allyl ynamides, Zhou, G.; Su,J.; Shang, T.; Wang, X.; Bai, Y.*; Yuan, Z.*; Zhu, G.* Org. Chem. Front.2021, 8, 4473-4478.

9. Transition-Metal-Free α Csp3−H Cyanation of Sulfonamides, Zhou, L.; Wei, S.; Lei, Z.;Zhu, G.*; Zhang, Z.*Chem. Eur. J. 2021,27, 7103-7107.

2020

10. Internal Alkyne-Directed Fluorination of Unactivated C(sp3)-H Bonds,Shu,C.;Feng, J.; Zheng, H.; Cheng, C.; Yuan, Z.; Zhang,Z.; Xue, X.-S.; Zhu, G.* Org. Lett. 2020, 22, 9398-9403.

11. Synthesis of Polysubstituted Pyrroles via Silver-Catalyzed Oxidative Radical Addition of Cyclopropanols to Imines,Zhou, Y.; Wu, M.; Liu, Y.; Cheng, C.; Zhu, G.* Org. Lett. 2020, 22, 7542-7546.

12. Visible-Light Photocatalytic RemoteHalo-Difluoroalkylation of Thioalkynes, Zhu, H.; Shang, T.;  Lu, Z.; Luo, F.; Zhu, G.*Chin. J. Org. Chem.2020, 40, 3410-3419 (invited paper,庆祝黄乃正先生七十华诞专辑).

13. AIBN-Induced Remote Trifluoromethyl-Alkynylation of Thioalkynes, Xiong,Z.; Zhang, F.; Yu, Y.; Tan, Z.; Zhu, G.* Org. Lett. 2020, 22, 4088-4092.

14. Photocatalytic Remote Oxyfluoroalkylation of Heteroalkynes: Regio-, Stereo-, and Site-Selective Access to Complex Fluoroalkylated (Z)-Alkenes, Shang,T.; Zhang,J.; Zhang,Y.; Zhang, F.; Li,X.-S.*; Zhu, G.* Org. Lett. 2020, 22,3667-3672.

2019

15. Visible-Light Photocatalytic Remote Thiolation of Aldehydes Triggered by Sulfonylation of Alkenes With Thiosulfonates, Yang, J.;Fu, X.; Lu, Z.;Zhu, G.* Acta Chim. Sinica 2019, 77, 901-905 (invited paper).

16. Photocatalytic 1,1-Hydrofluoroalkylation of Alkynes with A Concurrent Vicinal Acylation: An Access to Fluoroalkylated Cyclic Ketones, Wan, Y.; Shang, T.; Lu, Z. Zhu, G.* Org. Lett. 2019, 21,4187-4191.

17. Visible light photocatalytic acyldifluoroalkylation of unactivated alkenes for the direct synthesis of gem-difluorinated ketones, Zhou,Y.; Xiong, Z.;Qiu, J.; Kong, L.*;Zhu, G.* Org. Chem. Front.2019, 6, 1022-1026.

18. Modular Synthesis of Alkylarylazo Compounds via Iron(III)-Catalyzed Olefin Hydroamination,Zhang,Y.*; Huang, C.; Lin,X.; Hu, Q.; Hu,B.; Zhou,Y.; Zhu, G.* Org. Lett. 2019, 21,2261-2264.

19. Multicomponent Synthesis of Isoindolinones by RhIII Relay Catalysis:Synthesis of Pagoclone and Pazinaclone from Benzaldehyde, Zhang,Y.*; Zhu,H.; Huang,Y.; Hu,Q.; He,Y.; Wen,Y.; Zhu, G.* Org. Lett. 2019, 21,1273-1277.

2018

20. Recent Advances on Oxidative Radical Addition to Aldehydes, Kong, L.; Zhou, Y.; Luo, F.; Zhu, G.*Chin. J. Org. Chem.2018, 38, 2858-2865 (invited paper).

21. Palladium-Catalyzed anti-Selective Fluoroalkylboration of Internal and Terminal Alkynes, Wang, S.; Zhang, J.; Kong, L.; Tan, Z.; Bai, Y.*;Zhu, G.* Org. Lett. 2018, 20, 5631-5635.

22. Visible-light induced three-component alkynyl-difluoroalkylation of unactivated alkenes, Jin, W.; Wu, M.; Xiong, Z. Zhu, G.* Chem. Commun.2018, 54, 7924-7927.  

23. Synthesis of Difluoromethylated and Phosphorated Spiro[5.5]trienones via Dearomative Spirocyclization of Biaryl Ynones, Zhang, Y.*; Zhang, J.; Hu, B.; Ji, M.; Ye, S.; Zhu, G.* Org. Lett. 2018, 20, 2988-2992.

24. Photocatalytic acylarylation of unactivated alkenes with diaryliodonium salts toward indanones and related compounds, Chen, Y.; Shu, C.; Luo, F.; Xiao, X.;*Zhu, G.* Chem. Commun.2018, 54, 5373-5376.

25. Intermolecular Oxidative Radical Addition to Aromatic Aldehydes: Direct Access to 1,4- and 1,5-Diketones via Silver-Catalyzed Ring-Opening Acylation of Cyclopropanols and Cyclobutanols, Che, C.; Qian,Z.; Wu,M.; Zhao, Y.; Zhu, G.*J. Org. Chem. 2018, 83, 5665-5673.

26. Nickel-Catalyzed Remote Arylation of Alkenyl Aldehydes Initiated by Radical Alkylation with Tertiary α-Carbonyl Alkyl Bromides, Jin, W.; Zhou, Y.; Zhao,Y.;Ma, Q.; Kong, L.; Zhu, G.* Org. Lett. 2018, 20, 1435-1438.

27. Palladium-Catalyzed Site-Selective sp3 C-H Bond Thiocyanation of 2-Aminofurans, Chen, Y.; Wang, S.; Jiang, Q.; Cheng, C.;Xiao,X.;*Zhu, G.* J. Org. Chem. 2018, 83, 716-722.

2017

28. Preparation of 2-Amino-5-homoallylfurans via Palladium-Catalyzed Tandem Cycloisomerization/Heck-Type Coupling of Homoallenyl Amides with Allyltrialkylsilanes, Zhang, J.; Wu, M.; Lu, W.; Wang, S.; Zhang, Y.; Cheng, C.;*Zhu, G.* J. Org. Chem. 2017, 82, 11134-11140.

29. Palladium-catalyzed tandem cyclization/sulfonylation of homoallenyl amides with sodium sulfinates, Wan,Y.;Zhang, J.; Chen, Y.; Kong, L.; Luo, F.;* Zhu, G.*Org. Biomol. Chem.2017,15, 7204-7211.

30. Copper-Catalyzed Radical Cascade Difluoromethylation/Cyclization of 2-(3-Arylpropioloyl)benzaldehydes: A Route to Difluoromethylated Naphthoquinones, Zhang, Y.*; Ye, S.(本科生); Ji, M.; Li, L.; Guo, D.; Zhu, G.J. Org. Chem. 2017, 82, 6811-6818. 12

31. Visible Light-Induced Tandem Radical Addition-Cyclization of Alkenyl Aldehydes Leading to Indanones and Related Compounds,Lu, D.; Wan, Y.; Kong, L.; Zhu, G.*Org. Lett. 2017, 19, 2929-2932.

32. Copper-catalyzed acyltrifluoromethylation of alkenes: rapid access to trifluoroethyl indanones and related compounds, Liu, Z.; Bai, Y.; Zhang, J.; Yu, Y.; Tan, Z.; Zhu, G.*Chem. Commun.2017, 53, 6440-6443.  20

33. Palladium-Catalyzed Remote Aryldifluoroalkylation of Alkenyl Aldehydes, Nie, X.; Cheng, C.; Zhu, G.* Angew. Chem. Int. Ed.2017,56, 1898-1902.

34. Synthesis of Trifluoromethylated Naphthoquinones via Copper-Catalyzed Cascade Trifluoromethylation/Cyclization of 2-(3-Arylpropioloyl)benzaldehydes, Zhang, Y.;Guo, D.(本科生); Ye, S.; Liu, Z.; Zhu, G.*Org. Lett. 2017, 19, 1302-1305.

35. Copper-catalyzed borylative cyclization of 1,n-enynyl phosphates leading to five- to eight-membered cyclic 1,4-dienyl boronates, Zhang, F.; Wang, S.; Liu, Z.; Bai, Y.;*Zhu, G.* Tetrahedron Lett.2017, 58, 1448-1452.

2016

36. Synthesis of (E)-α,β-Unsaturated Carbonyls via Silver-Catalyzed Tandem Epoxide Rearrangement/Intermolecular Carbonyl-Heteroalkyne Metathesis,Zhu, H.; Jin, W.; He, J.; Zhang,Y.*;Zhu, G.* Adv. Synth. Catal. 2016, 358, 3730-3735.

37. Copper-catalyzed cascade annulation between α-bromocarbonyls andbiaryl or (Z)-arylvinylacetylenes enabling a direct synthesis of dibenzocycloheptanes and related compounds, Lu, D.; Wan, Y.; Kong, L.; Zhu, G.*Chem. Commun.2016, 52, 13971-13974.

38. Copper-Catalyzed Trifluoromethylation of Alkenes with Redox-Neutral Remote Amidation of Aldehydes, Cheng, C.; Liu, S.; Lu, D.; Zhu, G.* Org. Lett. 2016, 18, 2852-2855.

39. Copper-catalyzed cascade annulation of unsaturated α-bromocarbonyls with enynals: afacile access to ketones from aldehydes, Che, C.; Huang, Q.;Zheng, H.; Zhu, G.*Chem. Sci. 2016, 7, 4134-4139.

40. Direct access to 2-amino-5-azidomethylfurans through palladium-catalyzed azidative cycloisomerization of homoallenyl amides, Huang, Q.(本科生); Zheng, H.; Liu, S.; Kong, L.; Luo, F.*; Zhu, G.* Org. Biomol. Chem.2016,14, 8557-8563.

41. HOTf-Catalyzed, Solvent-free Oxyarylation of Ynol Ethers and Thioethers, Hu, L.; Cui, Q.; Chen, X.; Tan, Z.*; Zhu, G.* J. Org. Chem. 2016, 81, 4861-4868.

42. Copper-catalyzed coupling of 2-vinyl benzaldehydes with 3-alkenyl 2-bromocarbonyls for the rapid construction of 3,4-cyclopenta-1-tetralones, Zhu,H.; Nie,X.; Huang, Q.;ZhuG.*Tetrahedron Lett.2016, 57, 2331-2335.

43. Highly mono-selective ortho-trifluoromethylation of benzamidesvia 8-aminoquinoline assisted Cu-promoted C-H activations, Hu, L.; Chen, X.; Gui, Q.; Tan, Z.*, Zhu, G. Chem. Commun. 2016,52, 6845-6848.

2015

44. A rapid and selective synthesis of α,α-fluorohalo esters via fluorohalogenative or difluorinative hydration of ynol ethers, Hu, L.; Che, C.; Tan, Z.;* Zhu, G.* Chem. Commun. 2015, 51, 16641-16644.

45. Construction of 1-Naphthols via Benzannulation Based on the Reaction of Aryl tert-Butyl Ynol Ethers with Ynamides or Ynol Ethers, Bai, Y.; Yin, J.; Liu, Z.; Zhu, G.* J. Org. Chem. 2015, 80, 10226-10233.

46. Copper-Catalyzed trans-Carbohalogenation of Terminal Alkynes with Functionalized Tertiary Alkyl Halides, Che, C.; Zheng, H.; Zhu, G.* Org. Lett. 2015, 17, 1617-1620.

47. Palladium-Catalyzed Cycloisomerization and Aerobic Oxidative Cycloisomerization of Homoallenyl Amides: A Facile and Divergent Approach to 2-Aminofurans, Cheng, C.; Liu, S.; Zhu, G.* Org. Lett. 2015, 17, 1581-1584.

48. Copper-catalyzed regio- and stereoselective hydroallylation of thioalkynes with allylboronates: a facile and convenient synthesis of 1,4-dienes, Kong, W.; Che, C.; Kong, L.*; Zhu, G.* Tetrahedron Lett.2015, 56, 2780-2782.

49. Copper-Catalyzedβ-Selective Borylation of Ynamides: A Facile Access to (E)-β-Alkenylamide Boronates, Bai, Y.*; Zhang, F.; Shen, J.; Luo, F.; Zhu, G.*Asian J. Org. Chem.2015, 4, 626-629 (Dedicated to Prof. Ei-ichi Negishi on the occasion of his 80th birthday)

50. Divergent Synthesis of 2-Aminofurans via Palladium-Catalyzed Acetoxylative, Alkoxylative, and Hydroxylative Cycloisomerization of Homoallenyl Amides, Cheng, C.; Liu, S.; Zhu, G.* J. Org. Chem. 2015, 80, 7604-7612.

2014

51. Palladium-Catalyzed Cross Addition of Terminal Alkynes to Aryl Ynamides: AnUnusual trans-Hydroalkynylation Reaction, Liu, G.; Kong, W.; Che, J.; Zhu, G.* Adv. Synth. Catal. 2014, 356, 3314-3318.

52. Preparation of (Z)-α,β-Disubstituted Enamides via Palladium-Catalyzed Addition of Boronic Acids to Ynamides, Yang, Y.; Wang, L.; Zhang, F.; Zhu. G.*J. Org. Chem.2014, 79, 9319-9324.  

53.Silver-Catalyzed Regio- and Stereoselective Addition of Carboxylic Acids to Ynol Ethers, Yin, J.; Bai, Y.; Mao, M.; Zhu. G.*J. Org. Chem.2014, 79, 9179-9185.  

54. Silver-promoted trans-hydrofluorination of ynamides: a regio- and stereoselective approach to (Z)-α-fluoroenamides, Che, J.(本科生); Li, Y.; Zhang, F.; Zheng, R.*; Bai, Y.;Zhu. G.* Tetrahedron Lett.2014, 55, 6240-6242.  

55. Pd-Catalyzed Regio- and Stereoselective Addition of Boronic Acids to Silylacetylenes: A Stereodivergent Assembly of β,β-Disubstituted Alkenyl Silanes and Alkenyl Halides, Kong, W.; Che, C.; Wu, J.; Ma, L.; Zhu, G.*J. Org. Chem. 2014, 79, 5799-5805.  

56. Palladium-Catalyzed Hydroarylation, Hydroalkenylation, and Hydrobenzylation of Ynol Ethers with Organohalides: A Regio- and Stereoselective Entry to α,β- and β,β-Disubstituted Alkenyl Ethers, Cui, W.; Ying, J.;Zheng, R.; Cheng, C.; Bai, Y.Zhu, G.* J. Org. Chem. 2014, 79, 3487-3493.  

57. An unprecedented Pd-catalyzed trans-addition of boronic acids to ynamides. Yang, Y.; Wang, L.; Zhang, J.; Jin, Y.; Zhu, G.*Chem. Commun.2014, 50, 2347-2349.

58. Synthesis of cis-1,2-dichlorovinylsulfones via Fe-catalyzed regio- and stereoselective addition of sulfonyl chlorides to aromatic chloroalkynes. Wang, L.; Zhu, H.; Che, J.; Yang, Y.*; Zhu, G.*Tetrahedron Lett.2014, 55,1011-1013.

59. Synthesis of (Z)-1-Thio- and (Z)-2-Thio-1-alkenyl Boronates via Copper-Catalyzed Regiodivergent Hydroboration of Thioacetylenes: An Experimental and Theoretical Study. Zhu, G.*; Kong, W.; Feng, H.; Qian, Z.* J. Org. Chem. 2014, 79, 1786-1795.

60. A regio- and stereoselective entry to (Z)-β-halo alkenyl sulfides and their applications to the access of stereodefined trisubstituted alkenes. Liu, G.; Kong, L.; Shen, J.; Zhu, G.*Org. Biomol. Chem.2014, 12, 2310-2321.

2013

61. Palladium-Catalyzed Direct Alkenylation of 2-Oxazolones: An Entry to 3,4,5-Trisubstituted 2-Oxazolones, Lu, Z.; Luo, F.; Wang, L.; Zhu, G.* J. Org. Chem.2013, 78, 10894-10901.

62. Pd-catalyzed addition of boronic acids to ynol ethers: a highly regio- and stereoselective synthesis of trisubstituted vinyl ethers. Bai, Y.; Yin, J.; Kong, W.; Mao, M.; Zhu, G.*Chem. Commun.2013, 49, 7650-7652.

63. Regioselective and Stereoselective Entry to β,β-Disubstituted Vinyl Ethers via the Sequential Hydroboration/SuzukiMiyaura Coupling of Ynol Ethers. Cui, W.; Mao, M.; He, Z.; Zhu, G.*J. Org. Chem.2013, 78, 9815-9821.

64. Copper-catalyzed direct thiolation of xanthines and related heterocycles with disulfides. He, Z. (本科生); Luo, F.;* Li,Y.;Zhu, G.* Tetrahedron Lett. 2013,54, 5907-5910.

65. An operationally simple approach to (E)-α-halo vinyl sulfides and their applications for accessing stereodefined trisubstituted alkenes. Yang, Z.(本科生); Chen, X.; Kong, W.; Xia, S.; Zheng, R.; Luo, F.; Zhu, G.*Org. Biomol. Chem.2013, 11, 2175-2185.

2012

66. Highly stereoselective synthesis of (Z)-1,2-dihaloalkenes by a Pd-catalyzed hydrohalogenation of alkynyl halides. Zhu, G.*; Chen, D.; Wang, Y.; Zheng, R.Chem. Commun.2012, 48, 5796-5798.

67. Preparation of 3,4,5-Trisubstituted Oxazolones by Pd-Catalyzed Coupling of N-Alkynyl tert-Butyloxycarbamates with Aryl Halides and Related Electrophiles. Lu, Z.; Cui, W.; Xia, S.; Bai, Y.; Luo, F.; Zhu, G.*J. Org. Chem.2012, 77,9871-9877.

68. A Facile Access to 3,5-Disubstituted Oxazolones Featuring a Cu-catalyzed Cyclization of N-Alkynyl tert-Butyl Carbamates. Lu, Z.; Yang, Z.; Cui, W.; Zhu, G.*Chem. Lett.2012, 41, 636-638.

69. Approach to highly functionalized oxazolones by a Pd-catalyzed cyclization of N-alkynyl tert-butyloxycarbamates. Lu, Z.; Xu, X.; Yang, Z.; Kong, L.*; Zhu, G.*Tetrahedron Lett. 2012, 53, 3433-3436.

70. A Facile Method for the Synthesis of 3-Alkyloxindole. Du, T.; Zhu, G.*; Zhou, J.* Lett. Org. Chem.2012, 9, 225-232.

2011

71. Palladium-catalyzed haloallylation of aromatic ynol ethers with allyl chlorides: a highly regio- and stereoselective approach to (1E)-α-chloroenol ethers. Cai, H.(本科生); Yuan, Z.; Zhu, W.; Zhu, G.*Chem. Commun.2011, 47, 8682-8684.

72. Palladium-catalyzed highly regio- and stereoselective synthesis of (1E)- or (1Z)-1,2-dihalo-1,4-dienes via haloallylation of alkynyl halides. Chen, X.; Kong, W.; Cai, H.; Kong, L.; Zhu, G.*Chem. Commun. 2011,47,2164-2166.

73. Palladium-Catalyzed Dienylation of Haloalkynes Using 2,3-Butadienyl Acetates: A Facile Access to (1Z)-1,2-Dihalo-3-vinyl-1,3-dienes. Chen, D.; Chen, X.; Lu, Z.; Cai, H.; Shen, J.; Zhu, G.* Adv. Synth. Catal. 2011, 353, 1474-1478.

74. Synthesis of Multisubstituted Enamides via Pd-Catalyzed Chloroallylation of Ynamides. Lu, Z.; Kong, W.; Yuan, Z.; Zhao, X.; Zhu. G.* J. Org. Chem. 2011, 76, 8524-8529.

75. Palladium-Catalyzed Coupling of Haloalkynes with Allyl Acetate: A Highly Regio- and Stereoselective Synthesis of (Z)-β-Haloenol Acetates.Chen, X.; Chen, D.; Lu, Z.; Kong, L.; Zhu, G.* J. Org. Chem. 2011, 76, 6338-6343.

76. Synthesis of cis-1,2-Dihaloalkenes Featuring Palladium-Catalyzed Coupling of Haloalkynes andα,β-Unsaturated Carbonyls. Chen, D.; Cao, Y.; Yuan, Z.; Cai, H.; Zheng, R.; Kong, L.; Zhu, G.*J. Org. Chem. 2011,76, 4071-4074.

2010

77. Highly efficient and diastereoselective synthesis of 1,3-oxazolidines featuring a palladium-catalyzed cyclization reaction of 2-butene-1,4-diol derivatives and imines. Chen, D.; Chen, X.; Du, T.; Kong, L.; Zheng, R.; Zhen, S.; Wen, Y.; Zhu, G.*Tetrahedron Lett.2010, 51, 5131-5133.

学术报告:

1. Remote C-H functionalization initiated by radical addition to non-terminal alkynes,第三届全国有机自由基化学会议,武汉,2022.08.04

2. 自由基迁移引发的远程碳氢官能团化反应研究,第十七届江淮有机化学论坛,台州,2019.11.03

3. 炔烃自由基加成启动的远程碳-氢键官能团化反应,2019世界青年科学家峰会-绿色化学国际论坛,2019.10.26

4. 自由基迁移引发的远程醛基直接官能团化反应研究,届全国有机自由基化学会议深圳2019.04.14

5. 醛基的氧化自由基加成反应研究,第31届中国化学会学术年会,浙江杭州,2018.05.07

6. 远程醛基碳-氢键直接官能团化反应研究,第十届全国有机化学学术会议,广东深圳,2017.12.19

7. 醛直接转化为酮的催化自由基反应研究,第十五届全国均相催化学术讨论会,浙江杭州,2017.09.28

8. Transition-Metal-Catalyzed Radical Transformation of Aldehydes for the Synthesis of Carbonyl Compounds第一届全国有机自由基化学会议苏州,2017.11.04