陈德利，男，1982年5月出生于浙江苍南，理学博士，副研究员，硕士生导师。在化学与物理相关领域的国际知名期刊如Phys. Rev. Lett., Angew. Chem. Int. Ed.,Appl. Catal. B-Environ., Nano Res., J. Mater. Chem. A等发表学术论文60余篇。

ResearcherID: H-6867-2012

E-mail: chendl@zjnu.cn

办公室： 15幢239室

主要经历：

•  2017年1月-至今 浙师大含氟新材料研究所 副研究员

•  2013年7月-2016年12月 浙师大物理化学研究所 助理研究员、副研究员

•  2008年8月-2013年5月  美国匹兹堡大学 化工系 博士后 导师：J Karl Johnson教授

•  2003年9月-2008年7月  吉林大学 理论化学研究所 攻读博士学位 导师：

孙家钟院士、田维全教授

•  1999年9月-2003年6月 温州师范学院 物理与电子信息学院 物理学攻读学士学位

教学课程：

本科生《结构化学》、《物理化学实验》

研究生《化学统计热力学》

研究兴趣：

1. 单原子催化剂材料设计及其在加氢还原等重要反应中的催化反应机理研究。

2. 内嵌金属纳米团簇的金属有机骨架材料催化剂结构预测及反应机理研究。

3. 围绕在气体吸附和分离有潜在应用价值的金属有机骨架材料开展研究工作。

4. 含氟新材料结构与性能理论模拟。

主要承担研究课题：

1.  HF电子气体纯化原理及材料研究，科技部重点研发计划，2017.7-2020.6，146万元，主要参与人员；

2. 金属纳米粒子嵌入金属有机骨架材料形成机理的多尺度计算模拟，国家自然科学基金青年项目，2014.1-2016.12，25万元，负责人；

3. 硅石狭缝中甲烷水合物成核机理的分子动力学模拟研究，国家自然科学基金青年项目，2015.1-2017.12，25万元，主要参与人员；

4. 负载金属团簇锆基MOFs材料甲酸分解制氢机理研究，浙江省自然科学基金，2021.1-2023.12，10万元，负责人；

5. 固体吸附剂在水蒸气共存条件下的CO₂/N₂吸附分离性能实验研究与计算机模拟，2017.1-2019.12，9万元，负责人；

近几年主要学术论文：

1.  Yaping Song, Ruifang Xue, Li Wang, Nan Li, Zhijun Fang, Yanghe Fu, De-Li Chen,^* Weidong Zhu,^* Fumin Zhang,^* Subnanometric Pt Clusters Supported on MgO-Incorporated Porous Carbon as Efficient Metal-Base Bifunctional Catalysts for Reductive Heterocyclization Reactions, Green Chem.2023, 25, 1107.

2.  Maomao Ni, Yijia Zhu, Changfa Guo,^*De-Li Chen,^* Jiqiang Ning, Yijun Zhong, Yong Hu,^* Efficient Visible-Light-Driven CO₂ Methanation with Self-Regenerated Oxygen Vacancies in Co₃O₄/NiCo₂O₄ Hetero-Nanocages: Vacancy-Mediated Selective Photocatalysis, ACS Catal.2023, 13, 2502-2512.

3.  Nan Li, Changping Jian, Yaping Song, Li Wang, Ata Ur Rehman, Yanghe Fu, Fumin Zhang,^*De-Li Chen,^* Weidong Zhu,^* Scalable Synthesis of MIL-88A(Fe) for Efficient Aerobic Oxidation of Cyclohexene to 2-Cyclohexene-1-ol, Mol. Catal.2023, 535, 112899.

4.  Yijia Zhu, Changpin Jian, Ruifang Xue, Wei Zhang, Rou Guo, Yijing Gao, De-Li Chen,^* Fumin Zhang, Weidong Zhu, Fang-Fang Wang,^* Screening Single Metal Atom Doped M/C₂N Catalysts for C₂H₂ Semi-Hydrogenation: The Role of Frustrated Lewis Pair, J. Chem. Phys.2022, 157, 054704.

5.  Lei Li,^# Xinyan Dai,^#De-Li Chen,^# Yin Xiang Zeng, Yong Hu,^* Xiong-Wen (David) Lou,^* Steering Catalytic Activity and Selectivity of CO₂ photoreduction to Syngas with Hydroxy-Rich Cu₂S@ROH-NiCo₂O₃ Double-Shelled Nanoboxes, Angew. Chem. Int. Ed.2022, 134, e202205839.

6.  Changfa Guo, De-Li Chen,^* Yong Hu,^* Perspective on Defective Semiconductor Heterojunctions for CO₂ Photoreduction, Langmuir2022, 38, 6491-6498. (Invited perspective)

7.  Fang-Fang Wang, Rou Guo, Changping Jian, Wei Zhang, Ruifang Xue, De-Li Chen,^* Fumin Zhang, Weidong Zhu, Mechanism of Catalytic Transfer Hydrogenation for Furfural using Single Ni Atom Catalysts Anchored to Nitrogen-Doped Graphene Sheets, Inorg. Chem.2022, 61, 9138.

8.  Ying Yang,^#Deli Chen,^# Haiyan Wang,^* Pengcheng Ye, Zhentao Ping, Jiqiang Ning, Yijun Zhong, Yong Hu,^* Two-Step Nitrogen and Sulfur Doping in Porous Carbon Dodecahedra for Zn-Ion Hybrid Supercapacitors with Long Term Stability, Chem. Eng. J.2022, 431, 133250.

9.  Li Wang,^#Deli Chen,^# Shuqi Miao, Fang Chen,^* Changfa Guo, Pengcheng Ye, Jiqiang Ning, Yijun Zhong, Yong Hu,^* Nitric Acid-Assisted Growth of InVO4 Nanobelts on Protonated Uultrathin C₃N₄ Nanosheets as An S-scheme Photocatalyst with Tunable Oxygen Vacancies for Boosting CO₂ Conversion, Chem. Eng. J.2022, 434, 133867.

10.  Binbin Feng, Rou Guo, Qian Xu, Qiulan Cai, Yaping Song, Nan Li, Yanghe Fu, De-Li Chen,^* Junfa Zhu, Jiangwei Zhang,^* Weidong Zhu,^* Fumin Zhang,^* Construction of Isolated Ni sites on Nitrogen-Doped Hollow Carbon Spheres with Ni-N₃ Configuration for Enhanced Reduction of Nitroarenese, Nano Res., 2022, 15, 6001-6009.

11.  Nuoya Li, Xujian Chen, Jin Wang,^* Xinmeng Liang, Lintao Ma, Xiaolang Jing, De-Li Chen,^* Zhengquan Li,^*Eco-Friendly ZnSe Nanorods/CsSnCl₃ Perovskite Heterojunction for Photocatalytic CO₂ Reduction, ACS Nano, 2022, 16, 3332-3340.

12.  Chunlin Ye, Xujian Chen, Shasha Li, Binbin Feng, Yanghe Fu, Fumin Zhang,^*De-Li Chen,^* Weidong Zhu,^*PdZn Intermetallic Compound Stabilized on ZnO/nitrogen-Decorated Carbon Hollow Spheres for Catalytic Semihydrogenation of Alkynols, Nano Res., 2022, 15, 3090-3098.

13.  Ping Zhou, Lianglan Yue, Xinxin Wang, Lihui Fan, De-Li Chen,^* Yabing He,^* Improving Ethane/Ethylene Separation Performance of Isoreticular Metal-Organic Framework via Engineering, ACS Appl. Mater. Inter.2021, 13, 54059-54068.

14.  Xujian Chen, Chengcheng Kong, Huaquan Huang, De-Li Chen,^* Fang-Fang Wang,^* Fumin Zhang, Weidong Zhu, Mechanism of Selective Hydrogenation of 4-Nitrophenylacetylene Using Pt-Zn Intermetallic Nanoparticles: The Role of Hydrogen Coverage, J. Phys. Chem. C2021, 125, 23803-23812.

15.  Huaquan Huang, Changping Jian, Yijia Zhu, Rou Guo, Xujian Chen, Fang-Fang Wang,^*De-Li Chen,^* Fumin Zhang, Weidong Zhu, Single Non-Noble Metal Atom Doped C₂N Catalysts for Chemoselective Hydrogenation of 3-Nitrostyrene, Phys. Chem. Chem. Phys.2021, 23, 25761-25768.

16.  Lei Li, Changfa Guo, Jiqiang Ning, Yijun Zhong, De-Li Chen,^* Yong Hu,^* Oxygen-Vacancy-Assited Construction of FeOOH/CdS Heterostructure as An Efficient Bifunctional Photocatalyst for CO₂ Conversion and Water Oxidation, Appl. Catal. B-Environ.2021, 293, 120203. (Hot paper)

17.  Meng Zhang, Xujian Chen, Xinyan Jiang, Jin Wang,^* Liyun Xu, Junhao Qiu, Wenrong Lu, De-Li Chen,^* Zhengquan Li,^* Activate Fe₃S₄ nanorodes by Ni Doping for Efficient Dye-Sensitized Photocatalytic Hydrogen Production, ACS Appl. Mater. Inter.2021, 13, 14198-14206.

18.  Qiulan Cai, Qionghao Xu, Yunyi Zhang, Yanghe Fu, De-Li Chen,^* Jiangwei Zhang,^* Weidong Zhu,^* Fumin Zhang,^* Boosted Catalytic Hydrogenation Performance using Isolated Co Sites Anchored on Nitrogen-Incorporated Hollow Porous Carbon, J. Phys. Chem. C, 2021, 125, 5088-5098.

19.  Le Yang, Jinxu Huang, Jie Cen, De-LiChen,^* Hui Zeng, Zebao Rui,^* Rafael Luque,^* Peigao Duan, Lewid Acid (Ni²⁺, Co^2+/3+ or Zn²⁺) Modified Electron-Deficient Ir⁴⁺ in IrO₂/CuO for Promoting Methane Oxidation to Ethanol and Methanol, J. Mater. Chem. A, 2021, 9, 7094-7101.

20.  Zhenzhen Jiang, Lihui Fan, Ping Zhou, Tingting Xu, Simin Hu, Jingxian Chen, De-Li Chen,^* Yabing He,^* An Aromatic-Rich Cage-based MOF with Inorganic Chloride Ions Decorating the Pore Surface Displaying the Preferential Adsorption of C₂H₂ and C₂H₆ over C₂H₄, Inorg. Chem. Front.2021, 8, 1243-1252.

21.  Changfa Guo, Kunfei Tian, Li Wang, Feng Liang, Fang-Fang Wang, De-Li Chen,^* Jiqiang Ning, Yijun Zhong, Yong Hu,^*Approach of Fermi Level and Electron-Trap Level in Cadmium Sulfide Nanorods via Molybdenum Doping with Enhanced Carrier Separation for Boosted Photocatalytic Hydrogen Production, J. Coll. Interface Sci., 2021, 583, 661-671. (Highly cited paper)

22.  Zhenzhen Jiang, Lihui Fan, Ping Zhou, Tingting Xu, Jingxian Chen, Simin Hu, De-Li Chen,^* Yabing He,^* An N-oxide-functionalized nanocage-based copper-tricarboxylate framework for the selective capture of C₂H₂, Dalton Trans., 2020, 49, 15672-15681.

23.  Fang-Fang Wang, Qingwen Wang, Xujian Chen, De-Li Chen,^* Weidong Zhu, Theoretical Investigations on the Effect of the Functional Group of Pd@UiO-66 for Formic Acid Dehydrogenation, J. Phys. Chem. C,2020, 124, 23738-23744.

24.  Fang-Fang Wang, Feng Liang, Yunyi Zhang, Xujian Chen, De-LiChen,^* Weidong Zhu, Stabilities and electronic structures of transition metal (Cu, Ag, Au, Ni, Pd, Pt) clusger-confined UiO-66, J. Phys. Chem. C, 2020, 124, 28123-28131.

25.  Jie Cen, Feng Liang, De-Li Chen,^* Lulu Zhang, Ning Yang, Weidong Zhu, Adsorption of Water Molecule on Calcium Fluoride and Magnesium Fluoride Surface: A Combined Theoretical and Experimental Study, J. Phys. Chem. C, 2020, 124, 7853-7859.

26.  Tingting Xu, Zhenzhen Jiang, Puxu Liu, Haonan Chen, Xiaosi Lan, De-Li Chen,^* Libo Li, Yabing He,^* Immobilization of Oxygen Atoms in the Pores of Microporous Metal-Organic Frameworks for C₂H₂ Separation and Purification, ACS Appl. Nano Mater., 2020, 3, 2911-2919.

27.  Xiaoxia Gao, Haoyan Zhong, Yingying Zhang, Yongna Yao, De-Li Chen,^* Yabing He,^* A Microporous MOF with Inorganic Nitrate Ions Immobilized on a Porous Surface Displaying Efficient C₂H₂ Separation and Purification, Euro. J. Inorg. Chem.2020, 1683-1689.

28.  Zhi Tian, De-Li Chen,^* Ting He, Pengyong Yang, Fang-Fang Wang,^* Yijun Zhong, and Weidong Zhu, Theoretical Evidence on the Confinement Effect of Pt@UiO-66-NH₂ for Cinnamaldehyde Hydrogenation, J. Phys. Chem. C, 2019, 123, 22114-22122.

29. De-Li Chen, Yan Sun, Mengyuan Chen, Xiaojin Li, Lei Zhang, Xin Zhang, Yihui Bai, Fang Luo, and Bo Peng, Desulfurization of Diaryl(heteroaryl) Sulfoxides with Benzyne, Org. Lett., 2019, 21, 3986-2989.

30.  Li Dou, Shengnan Wu, De-Li Chen,^* Sihui He, Fang-Fang Wang,^* and Weidong Zhu, Structures and Electronic Properties of Au Clusters Encapsulated ZIF-8 and ZIF-90, J. Phys. Chem. C, 2018, 122, 8901-8909.

31.  Yao Wang, Minghui He, Zhi Tian, Haoyan Zhong, Lisha Zhu, Yingying Zhang, Xiaoping Zhang, De-Li Chen,^* and Yabing He,^*Dalton Trans.2018, 47, 2444-2452.

32. De-Li Chen, Shengnan Wu, Pengyong Yang, Sihui He, Li Dou, Fang-Fang Wang,^* Ab initio molecular dynamic simulations on Pd clusters confined in UiO-66-NH₂, J. Phys. Chem. C, 2017, 121, 8857-8863.

33.  Shuang Zheng, Pengyong Yang, Fumin Zhang,^*De-Li Chen,^* Weidong Zhu, Pd nanoparticles encaged within amine-functionalized metal-organic frameworks: catalytic activity and reaction mechanism in the hydrogenation of 2,3,5-trimethylbenzoquinone, Chem. Eng. J.,2017, 328, 977-987.

34.  Jingjing Jiao, Li Dou, Huimin Liu, Fengli Chen, Dongjie Bai, Yunlong Feng, Shunshun Xiong, De-Li Chen,^* and Yabing He,^*Dalton Trans., 2016, 45, 13373-13382.

35.  Chengling Song, Yajing Ling, Liting Jin, Mingxing Zhang, De-Li Chen,^* and Yabing He,^* CO₂ adsorption of three isostructural metal-organic frameworks depending on the incorporated highly polarized heterocyclic moieties，Dalton Trans., 2016, 45, 190-197.

36.  Chengling Song, Jiayi Hu, Yajing Ling, Yunlong Feng, De-Li Chen,^* and Yabing He,^* Merging open metal sites and Lewis basis sites in a NbO-type metal-organic framework for improved C₂H₂/CH₄ and CO₂/CH₄ separation, Dalton Trans., 2015, 44, 14823-14829.

37.  Chengling Song, Jiayi Hu, Yajing Ling, Yunlong Feng, Rajamani Krishna,^*De-Li Chen,^* and Yabing He,^* The accessibility of nitrogen sites makes a difference in selective CO₂ adsorption of a family of isostructural metal-organic frameworks, J. Mater. Chem. A, 2015, 3, 19417-19426.

38. De-Li Chen, Ningwei Wang, Chunhui Xu, Gaomei Tu, Weidong Zhu,^* Rajamani Krishna,^* A combined theoretical and experimental analysis on transient breakthroughs of C₂H₆/C₂H₄ in fixed beds packed with ZIF-7, Micropor. Mesopor. Mater.2015, 208, 55-65.

39. De-Li Chen, Ningwei Wang, Fang-Fang Wang, Jianwu Xie, Yijun Zhong, Weidong Zhu,^* J Karl Johnson, and Rajamani Krishna,^* Utilizing the Gate-Opening Mechanism in ZIF-7 for Adsorption Discrimination between N₂O and CO₂, J. Phys. Chem. C, 2014, 118, 17831-17837.

40. De-Li Chen, Hao Shang, Weidong Zhu,^* Rajamani Krishna,^* Transient breakthroughs of CO₂/CH₄ and C₃H₆/C₃H₈ mixtures in fixed beds packed with Ni-MOF-74, Chem. Eng. Sci.2014, 117, 407-415.

41. De-Li Chen, Lynn Mandeltort, Wissam A. Saidi, John T. Yates, Jr.,^* Milton W. Cole, and J. Karl Johnson,^* Is there a difference in van der Waals interactions between rare gas atoms adsorbed on metallic and semiconducting single walled carbon nanotubes? Physical Review Letter, 2013, 110, 135503.

42.  Lynn Mandeltort, De-Li Chen, Wissam A. Saidi, J. Karl Johnson,^* Milton W. Cole, and John T. Yates, Jr.,^* Experimental and Theoretical Comparison of Gas Desorption Energies on Metallic and Semiconducting Single-Walled Carbon Nanotubes, J. Am. Chem. Soc., 2013, 135, 7768.

43.  Tao Li, De-Li Chen, Jeanne Sullivan, Mark kozlowski, and J. Karl Johnson, Nathaniel Rosi,^* Systematic modulation and enhancement of CO₂:N₂ selectivity and water stability in an isoreticular series of bio-MOF-11 analogues, Chemical Science, 2013, 4, 1746-1755.

44. De-Li Chen, W. A. Al-Saidi, and J. Karl Johnson,^* The role of van der Waals interactions in the adsorption of noble gases on metal surfaces, Journal of Physics: Condensed Matter, 2012, 24, 424211.

45. De-Li Chen, W. A. Al-Saidi, J. Karl Johnson,^* Noble Gases on Metal Surfaces: New Insights on Adsorption Site Preference, Physical Review B (Rapid Communication), 2011, 84, 241405.

46. De-Li Chen, Abraham C. Stern, Brian Space, and J. Karl Johnson,^* Atomic Charges Derived from Electrostatic Potentials for Molecular and Periodic Systems, Journal of Physical Chemistry A, 2010, 114, 10225.