张振华

发布日期：2021-01-19 阅读次数：4907

基本资料

张振华，男，1990年生，博士，校“双龙”特聘教授，硕士生导师。Email: zhangzh@zjnu.edu.cn；办公室：后勤楼309房间。

本课题组长期从事气-固多相催化反应固体催化剂表界面结构调控及催化作用研究，通过精准调控氧化物暴露晶面（表面）、氧化物-金属/氧化物复合催化剂界面及被负载金属/氧化物粒子尺寸等方式来研究催化剂在反应中的构效关系，并结合（准）原位表征手段理解催化反应机理，为高效催化剂研制提供理论基础。

目前已发表研究论文30篇，包括以第一或通讯作者身份在Nat. Commun.(2), J. Am. Chem. Soc., Angew. Chem. Int. Ed., ACS Catal.和J. Catal.等SCI期刊上发表研究论文近20篇，申请/授权国家发明专利5项，撰写英文专著章节1篇。

主要研究方向

1. 碳一小分子（CO和CO2）消除和催化转化

2. 烷烃（乙烷、丙烷）脱氢

◆承担项目

1. 国家自然科学基金青年项目：水煤气变换反应高效倒载型ZnO/Cu催化剂研制及催化作用机制，2022.01-2024.12，在研

2. 浙江省自然科学基金项目：CeO₂/Cu倒载型纳米晶催化剂的构筑及其在水汽变换反应和CO₂加氢到甲醇反应中的应用，2020.01-2022.12，在研

3. 催化基础国家重点实验室开放基金，2021.01-2022.12，在研

4. 先进催化材料国家重点实验室开放基金，2021.01-2022.12，在研

5. 浙江师范大学自主设计项目，2022.01-2024.12，在研

6. 浙江师范大学高层次人才引进启动经费，2020.01-2023.12，在研。

◆研究论文和专著

2021年

30. Z. Zhang,* L. Fan, W. Liao, F. Zhao, C. Tang, J. Zhang, M. Feng, J.-Q. Lu,* Structure sensitivity of CuO in CO oxidation over CeO₂-CuO/Cu₂O catalysts, J. Catal. 2022, Just accepted.

29. Z. Zhang, R. You, W. Huang, Cu₂O nanocrystal model catalyst, Chin. J. Chem. 2022, Just accepted.

28. W. Xiong, X. Gu, Z. Zhang, P. Chai, Y. Zang, Z. Yu, D. Li, H. Zhang, Z. Liu, W. Huang*, Fine cubic Cu₂O nanocrystals as highly selective catalyst for propylene epoxidation with molecular oxygen. Nat. Commun. 2021, 12, 5921.

27.J. Zhang, W. Liao, H. Zheng, Y. Zhang, L. Xia, B. Teng, J. Lu, W. Huang, Z. Zhang,* Morphology-engineered highly active and stable Pd/TiO₂ catalysts for CO₂ hydrogenation into formate, J. Catal. 2022, 405, 152-163.

26. Z. Zhang, X. Chen, J. Kang, Z. Yu, J. Tian, Z. Gong, A. Jia, R. You, K. Qian, S. He, B. Teng, Y. Cui, Y. Wang,* W. Zhang,* W. Huang,* Identification of the active sites of Cu-ZnO catalysts for water gas shift and CO hydrogenation reactions, Nat. Commun.2021, 12, 4331.

25. Q. Su, Z. Zhang, N. Yan, CO₂ Hydrogenation to Oxygenated Chemicals Over Supported Nanoparticle Catalysts: Opportunities and Challenges, 2021, ISBN: 9783527821761 (Book chapter).

24. L. Fan, J. Zhang, K. Ma, Y. Zhang, Y.-M. Hu, L. Kong, Z. Zhang,* W. Huang, J.-Q. Lu,* Ceria morphology-dependent Pd-CeO₂ interaction and catalysis in CO₂ hydrogenation into formate, J. Catal.2021,397, 116-127.

23. A. Jia, Y. Zhang, T. Song, Z. Zhang, C. Tang, Y. Hu, W. Zheng, M. Luo, J. Lu, W. Huang, Crystal-plane effects of anatase TiO₂ on the selective hydrogenation of crotonaldehyde over Ir/TiO₂ catalysts, J. Catal. 2021, 395, 10-22.

2020年

22. Z. Zhang,^#* Z.-Q. Wang,^# Z. Li,^# W.-B. Zheng,^# L. Fan, J. Zhang, Y.-M. Hu, M.-F. Luo, X.-P. Wu, X.-Q. Gong,* W. Huang,* J.-Q. Lu,* Metal-Free Ceria Catalysis for Selective Hydrogenation of Crotonaldehyde, ACS Catal.2020, 10, 14560-14566.

21. Z. Zhang,* J. Zhang, A.-P. Jia, J.-Q. Lu, W. Huang,* Morphology-Dependent CO Reduction Kinetics and Surface Copper Species Evolution of Cu₂O Nanocrystals, J. Phys. Chem. C2020, 124, 21568-21576.

20. Z. Yu, Z. Zhang,* Y. Zhang, W. Huang,* Titania Morphology-Dependent Catalysis of CuO_x/TiO₂ Catalysts in CO Oxidation and Water Gas Shift Reactions, ChemCatChem2020, 12, 3679-3686.

19. J. Zhang, L. Fan, F. Zhao, Y. Fu, J.-Q. Lu, Z. Zhang,* B. Teng,* W. Huang,* Zinc Oxide Morphology-Dependent Pd/ZnO Catalysis in Base-Free CO₂ Hydrogenation into Formic Acid, ChemCatChem2020, 12, 5540-5547.

18. Y. Gao,^#Z. Zhang,^# Z. Li, W. Huang,* Understanding Morphology-Dependent CuO_x-CeO₂ Interactions from the very Beginning, Chin. J. Catal.2020, 41, 1006-1016.

17. Z. Zhang,* L. Fan, Y.-J. Wang, Applications of Chemical Kinetics in Heterogeneous Catalysis. ISBN: 978-1-78984-890-8. (Invited book chapter).

16. T. Cao, R. You, Z. Li, X. Zhang, D. Li, S. Chen, Z. Zhang, W. Huang,* Morphology-Dependent CeO₂ Catalysis in Acetylene Semihydrogenation Reaction, Appl. Surf. Sci.2020, 501, 144120.

15. I.M. Denekamp, C. Deacon-Price, Z. Zhang, G. Rothenberg,* Covalent structured catalytic materials containing single-atom metal sites with controllable spatial and chemical properties: concept and application, Catal. Sci. Technol.2020, 10, 6694-6700.

2019年及以前（博士和博士后阶段）

14. Z. Zhang, L. Zhang, S. Yao, X. Song, W. Huang, M.J. Hülsey,* N. Yan,* Support-dependent rate-determining step of CO₂ hydrogenation to formic acid on metal oxide supported Pd catalysts, J. Catal.2019, 376, 57-67.

13. Z. Zhang,* L. Zhang, M.J. Hülsey, N. Yan,* Zirconia phase effect in Pd/ZrO₂ catalyzed CO₂ hydrogenation into formate, Mole. Catal.2019, 475, 110461.

12. Z. Zhang, H. Wu, Z. Yu, R. Song, K. Qian, X. Chen, J. Tian, W. Zhang, W. Huang,* Site-Resolved Cu₂O Catalysis in the Oxidation of CO, Angew. Chem. Int. Ed.2019, 58, 4276-4280.

11. Z. Zhang,* R. Song, Z. Yu, W. Huang,* Crystal-plane effect of Cu₂O templates on compositions, structures and catalytic performance of Ag/Cu₂O nanocomposites, CrystEngComm2019, 21, 2002-2008.

10. D. Li, R. You, M. Yang, Y. Liu, K. Qian, S. Chen, T. Cao, Z. Zhang, J. Tian, W. Huang,* Morphology-Dependent Evolutions of Sizes, Structures, and Catalytic Activity of Au Nanoparticles on Anatase TiO₂ Nanocrystals, J. Phys. Chem. C2019, 123, 10367-10376.

9. M. Yang, R. You, D. Li, Z. Zhang, W. Huang, Methanol Partial Oxidation Over Shaped Silver Nanoparticles Derived from Cubic and Octahedral Ag₂O Nanocrystals, Catal. Lett. 2019, 149, 2482-2491.

8. T. Cao, R. You, X. Zhang, S. Chen, D. Li, Z. Zhang, W. Huang, An in situ DRIFTS mechanistic study of CeO₂-catalyzed acetylene semihydrogenation reaction, Phys. Chem. Chem. Phys.2018, 20, 9659-9670.

7. D. Li, S. Chen, R. You, Y. Liu, M. Yang, T. Cao, K. Qian, Z. Zhang, J. Tian, W. Huang,* Titania-morphology-dependent dual-perimeter-sites catalysis by Au/TiO₂ catalysts in low-temperature CO oxidation, J. Catal.2018, 368, 163-171.

6. M. Yang, J. Zhang, Y. Cao, M. Wu, K. Qian, Z. Zhang, H. Liu, J. Wang,* W. Chen,* W. Huang,* Facet Sensitivity of Capping Ligand-Free Ag Crystals in CO₂ Electrochemical Reduction to CO, ChemCatChem2018, 10, 5128-5134.

5. Z. Zhang, S.-S. Wang, R. Song, T. Cao, L. Luo, X. Chen, Y. Gao, J. Lu, W.-X. Li, W. Huang,* The most active Cu facet for low-temperature water gas shift reaction, Nat. Commun.2017, 8, 488.

4. Z. Zhang, R. Song, T. Cao, W. Huang, Morphology-dependent structures and catalytic performances of Au nanostructures on Cu₂O nanocrystals synthesized by galvanic replacement reaction, J. Energy Chem.2016, 25, 1086-1091.

3. Z. Zhang, T. Cao, L. Luo, R. Song, H. Wang, W. Huang,* Au-Cu Alloy Formation on Cubic Cu₂O Nanocrystals at Ambient Temperature and Their Catalytic Performance, ChemNanoMat2016, 2, 861-865.

2. Y. Bai,^# W. Zhang,^#Z. Zhang,^# J. Zhou, X. Wang, C. Wang, W. Huang,* J. Jiang,* Y. Xiong,* Controllably Interfacing with Metal: A Strategy for Enhancing CO Oxidation on Oxide Catalysts by Surface Polarization, J. Am. Chem. Soc.2014, 136, 14650-14653.

1. H. Bao,^#Z. Zhang,^# Q. Hua, W. Huang,* Compositions, Structures, and Catalytic Activities of CeO₂@Cu₂O Nanocomposites Prepared by the Template-Assisted Method, Langmuir2014, 30, 6427-6436.

◆授权发明专利