STM-Raman界面电化学课题组
王亚浩, 1990年生,博士,副教授,硕士生导师,浙江师范大学(2019.10-至今)
已在国际期刊上发表学术论文39篇,其中以第一作者或通讯作者身份21篇,包括 Angew. Chem. Int. Ed (3篇)、 J. Phys. Chem. Lett.、Anal. Chem.、ACS Appl. Mater. Interfaces、 J. Mater. Chem. C、Electrochim. Acta、Chem. Commun.等;撰写英文专著章节一章;获第三届校思政微课一等奖(2022);指导本科生获第十三届浙江省大学生化学竞赛一等奖(2022),目前担任SCI期刊《Biosensors》、《Materials》的Topic Editor。
Email:yahaowang@zjnu.edu.cn办公室:11幢218室
个人主页:http://mypage.zjnu.edu.cn/yahaowang/zh_CN/index.htm
课题组组长:周小顺研究员国家****拔尖人才
其他成员:万强博士
教育经历:
2015.06 – 2019.09 厦门大学 博士 导师:李剑锋教授 国家****人才、杰青、优青、青千, https://jfli.xmu.edu.cn/ )
2018.09 – 2019.03 American University交流
2012.09 – 2015.06 浙江师范大学 硕士 导师:周小顺 研究员
2008.09 – 2012.06 安徽师范大学 材料化学 / 学士
研究方向:
研究方向一:表面增强拉曼光谱、电化学、电催化等。
研究方向二:STM裂结技术进行单分子电子学研究,探索单分子尺度的催化反应、分子组装行为、传感等。
欢迎有激情,敢创新,勤动手,善思考的同学加入我们课题组~
(课题组正处在快速发展阶段,学习机会多多!)
主持科研项目:
1. 国家自然科学基金青年项目, 2022-01至2024-12, 30万元, 在研
2. 浙江省自然科学基金探索项目, 2021-01至2023-12, 10万元, 在研
3. 先进催化材料”教育部重点实验室、“固体表面反应化学”省重点实验室2020年度开放课题基金一项, 已结题
4.浙江师范大学青年博士专项和科研启动经费
本科生教育
1. 《物理化学》、《文献检索与科技论文写作》课程、物理化学实验
2. 2020年浙江师范大学国家级大学生创新创业训练计划项目
发表文章
2023年
39.Yan, L.; Xie, B.; Yang, C.; Wang, Y.-H.; Ning, J.; Zhong, Y.; Hu, Y. *, Engineering Self‐Supported Hydrophobic–Aerophilic Air Cathode with CoS/Fe3 S4 Nanoparticles Embedded in S, N Co‐Doped Carbon Plate Arrays for Long‐Life Rechargeable Zn–Air Batteries. Advanced Energy Materials 2023,https://doi.org/10.1002/aenm.202204245
38.Zhou, Y.-H.; Jiang, C.-C.; Yu, Z.; Wang, Y.-H. *(通讯); Zheng, J.*; Zhou, X.-S.*, In situ Raman monitoring of electroreductive dehalogenation of aryl halide at Ag/aqueous solution interface. Analytical Methods2023, https://doi.org/10.1039/D2AY02060B
37.Wang, Y.-H.; Yu, Z.; Lv, S.-L.; Zheng, J.-F.; Zhou, X.-S., Probing solid/liquid interfaces at a single-molecule level by in-situ break junction techniques. In Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, Elsevier: 2023,https://doi.org/10.1016/B978-0-323-85669-0.00023-4 (书章节)
36.Fan, X.*; Zhong, R.; Huang, Y.; Zhou, X.; Zhu, X.; Zhan, L.; Zhou, X.*; Wang, Y.-H.*(通讯); Wang, X., Oxygen defect-rich MnOOH nanorod as an effective modulator to boost polysulfide reaction kinetic for high-performance lithium sulfur battery. Applied Surface Science2023, 614, 155869.
2022年
35. Lv, S. L.; Zeng, C.; Yu, Z.; Zheng, J. F.; Wang, Y. H.*(通讯); Shao, Y.; Zhou, X. S.*, Recent Advances in Single-Molecule Sensors Based on STM Break Junction Measurements. Biosensors 2022, 12(8), 565; https://doi.org/10.3390/bios12080565
34. Fu, J.-Y.(本科生一作); Li, X.-C.; Yu, Z.; Huang-Fu, X.-N.; Fan, J.-A.; Zhang, Z.-Q.; Huang, S.; Zheng, J.-F.; Wang, Y.-H.*(通讯); Zhou, X.-S., In Situ Raman Monitoring of Potential-Dependent Adlayer Structures on the Au(111)/Ionic Liquid Interface. Langmuir 2022,https://doi.org/10.1021/acs.langmuir.2c00703
33. Tong, L.; Bao, S.-Y.; Jiang, C.-C.; Li, X.-C.; Li, J.-J.; Huang-Fu, X.-N.; Zheng, J.; Shao, Y.; Wang, Y.-H.*(通讯); Gao, Y.*; Zhou, X.-S.*, Tuning the binding configurations of single-molecule junctions by molecular co-assembly. Chemical Communications 2022, 58, 4962–4965。
32.Zhang, L.; Su, L.-Z.; Yu, Z.; Su, L.-Y.; Zheng, Y.; Song, P.; Wang, Y.-H.*(通讯); Pan, Y.-B.; Zheng, B., Quantitative Detection of Creatinine in Human Serum by SERS with Evaporation-Induced Optimal Hotspots on Au Nanocubes. ACS Applied Nano Materials 2022. 5, 4841−4847
31.Jiang, C.-C.; Li, X.-C.; Fan, J.-A.; Fu, J.-Y.; Huang-Fu, X.-N.; Li, J.-J.; Zheng, J.-F.; Zhou, X.-S.; Wang, Y.-H.*(通讯), Electrochemically activated carbon–halogen bond cleavage and C–C coupling monitored by in situ shell-isolated nanoparticle-enhanced Raman spectroscopy. Analyst 2022, 147,1341-1347.
30.Yu, Z.; Li, J. Q.; Wang, Y.-H.*(通讯); Su, J. Q.; Fu, J. Y.; Zou, J. W.; Zheng, J. F.; Shao, Y.; Zhou, X. S., Visualizing an Electrochemically Induced Radical Cation of Bipyridine at Au(111)/Ionic Liquid Interfaces toward a Single-Molecule Switch. Analytical Chemistry 2022,94 (3), 1823-1830.
29.Seng, J.-W.; Tong, L.; Peng, X.-Q.; Chang, W.-Y.; Xie, W.; Wang, Y.-H.; Zheng, J.-F.; Shao, Y.; Chen, J.-Z.; Jin, S.; Zhou, X.-S., Influence of a Coordinated Metal Center on Charge Transport through a Series of Porphyrin Molecular Junctions. The Journal of Physical Chemistry C 2022,126 (2), 1168-1175.
28.Xu, Y.; Li, B.; Zhang, J.; Bai, G.; Zhang, X.; Hao, Q.; Wang, Y.-H.; Zhou, X.; Teng, B.; Liu, X., Exploration of Metal-Molecule interaction of subnanometric heterogeneous catalysts via simulated Raman spectrum. Applied Surface Science 2022,579, 152194.
27.Zhou, Y. F.; Chang, W. Y.; Chen, J. Z.; Huang, J. R.; Fu, J. Y.; Zhang, J. N.; Pei, L. Q.; Wang, Y. H.; Jin, S.; Zhou, X. S., Substituent-mediated quantum interference toward a giant single-molecule conductance variation. Nanotechnology 2022,33 (9),095201..
2021年
26.Qiu, J. P.; Xie, H. Q.; Wang, Y. H.; Yu, L.; Wang, F. Y.; Chen, H. S.; Fei, Z. X.; Bian, C. Q.; Mao, H.; Lian, J. B., Facile Synthesis of Uniform Mesoporous Nb2O5 Micro-Flowers for Enhancing Photodegradation of Methyl Orange. Materials 2021,14 (14).
25.Wang, Y. H.; Zhou, Y. F.; Tong, L.; Huang, H.; Zheng, J. F.; Xie, W.; Chen, J. Z.; Shao, Y.; Zhou, X. S., Revealing Supramolecular Interactions and Electron Transport in Single Molecular Junctions of Cucurbit[ n ]uril. Advanced Electronic Materials 2021,7 (9), 2100399.
24.Li, J.-J.; Chen, Z.-B.; Wang, Y.-H.; Zhou, X.-S.; Xie, L.-Q.; Shi, Z.; Liu, J.-X.; Yan, J.-W.; Mao, B.-W., Single-molecule anisotropic magnetoresistance at room temperature: Influence of molecular structure. Electrochimica Acta 2021,389, 138760.
23.Yu, Z.; Xu, Y.-X.; Su, J.-Q.; Radjenovic, P. M.; Wang, Y.-H.*(通讯); Zheng, J.-F.; Teng, B.; Shao, Y.; Zhou, X.-S.; Li, J.-F., Probing Interfacial Electronic Effects on Single-Molecule Adsorption Geometry and Electron Transport at Atomically Flat Surfaces. Angewandte Chemie International Edition 2021,60 (28), 15452-15458.
22.Jun-Qing Su, Y.-F. Z., Ling Tong, Ya-Hao Wang, Ju-Fang Zheng, Jing-Zhe Chen, Xiao-Shun Zhou, Electrochemical Gating Single-Molecule Circuits with Parallel Paths. Journal of Electrochemistry 2021,27 (2), 195-201.
21.Li, X. M. #; Wang, Y.-H.# (共一); Seng, J. W.; Zheng, J. F.; Cao, R.; Shao, Y.; Chen, J. Z.; Li, J. F.; Zhou, X. S.; Mao, B. W., z-Piezo Pulse-Modulated STM Break Junction: Toward Single-Molecule Rectifiers with Dissimilar Metal Electrodes. ACS Appl Mater Interfaces 2021,13 (7), 8656-8663.
20.Wang, Y. H.; Yan, F.; Li, D. F.; Xi, Y. F.; Cao, R.; Zheng, J. F.; Shao, Y.; Jin, S.; Chen, J. Z.; Zhou, X. S., Enhanced Gating Performance of Single-Molecule Conductance by Heterocyclic Molecules. Journal of Physical Chemistry Letters 2021,12 (2), 758-763.
2020年
19.Tao, C. P.; Jiang, C. C.; Wang, Y.-H.*(通讯); Zheng, J. F.; Shao, Y.; Zhou, X. S., Single-Molecule Sensing of Interfacial Acid-Base Chemistry. Journal of Physical Chemistry Letters 2020,11 (23), 10023-10028.
18.Wang, Y.-H.; Huang, H.; Yu, Z.; Zheng, J.-F.; Shao, Y.; Zhou, X.-S.; Chen, J.-Z.; Li, J.-F., Modulating electron transport through single-molecule junctions by heteroatom substitution. Journal of Materials Chemistry C 2020,8 (20), 6826-6831.
17.Zhang, F.; Wu, X. H.; Zhou, Y. F.; Wang, Y. H.; Zhou, X. S.; Shao, Y.; Li, J. F.; Jin, S.; Zheng, J. F., Improving Gating Efficiency of Electron Transport through Redox‐Active Molecular Junctions with Conjugated Chains. ChemElectroChem 2020,7 (6), 1337-1341.
工作以前Before
16.Wang, Y. H.; Le, J. B.; Li, W. Q.; Wei, J.; Radjenovic, P. M.; Zhang, H.; Zhou, X. S.; Cheng, J.; Tian, Z. Q.; Li, J. F., In situ Spectroscopic Insight into the Origin of the Enhanced Performance of Bimetallic Nanocatalysts towards the Oxygen Reduction Reaction (ORR). Angewandte Chemie 2019,58 (45), 16062-16066.
15.Wang, Y.-H.; Liang, M.-M.; Zhang, Y.-J.; Chen, S.; Radjenovic, P.; Zhang, H.; Yang, Z.-L.; Zhou, X.-S.; Tian, Z.-Q.; Li, J.-F., Probing Interfacial Electronic and Catalytic Properties on Well-Defined Surfaces by Using InSitu Raman Spectroscopy. Angewandte Chemie International Edition 2018,57 (35), 11257-11261.
14.Liang, M.-M. #; ; Wang, Y.-H.# (共一); Shao, R.; Yang, W.-M.; Zhang, H.; Zhang, H.; Yang, Z.-L.; Li, J.-F.; Tian, Z.-Q., In situ electrochemical surface-enhanced Raman spectroscopy study of CO electrooxidation on PtFe nanocatalysts. Electrochemistry Communications 2017,81, 38-42.
13.Zhang, H.; Zhang, X. G.; Wei, J.; Wang, C.; Chen, S.; Sun, H. L.; Wang, Y. H.; Chen, B. H.; Yang, Z. L.; Wu, D. Y.; Li, J. F.; Tian, Z. Q., Revealing the Role of Interfacial Properties on Catalytic Behaviors by in Situ Surface-Enhanced Raman Spectroscopy. J Am Chem Soc 2017,139 (30), 10339-10346.
12.Wen, B. Y.; Jin, X.; Li, Y.; Wang, Y. H.; Li, C. Y.; Liang, M. M.; Panneerselvam, R.; Xu, Q. C.; Wu, D. Y.; Yang, Z. L.; Li, J. F.; Tian, Z. Q., Shell-isolated nanoparticle-enhanced Raman spectroscopy study of the adsorption behaviour of DNA bases on Au(111) electrode surfaces. Analyst 2016,141 (12), 3731-6.
11.Wen, B.-Y.; Yi, J.; Wang, Y.-H.; Madasamy, K.; Zhang, H.; Kathiresan, M.; Li, J.-F.; Tian, Z.-Q., In-situ monitoring of redox processes of viologen at Au(hkl) single-crystal electrodes using electrochemical shell-isolated nanoparticle-enhanced Raman spectroscopy. Electrochemistry Communications 2016,72, 131-134.
10.Chen, Z. B.; Hong, Z. W.; Li, D. F.; Wang, Y. H.; Zhou, X. S., The conductance of pyridine-based molecules measured in ambient air and electrolyte solution: Effect of surrounding. International Journal of Electrochemical Science 2015,10 (4), 2931-2938.
9.Han, D.; Hong, Z. W.; Li, D. F.; Zheng, J. F.; Wang, Y. H.; Zhou, X. S., Single-Molecule Junction Conductance of Terephthalic Acid Contacting Ag and Cu Electrodes Measured by an Electrochemical Method. ACTA PHYSICO-CHIMICA SINICA 2015,31 (1), 105-110.
8.Hong, Z.-W.; Chen, F.; Wang, Y.-H.; Mao, J.-C.; Li, D.-F.; Tang, Y.; Shao, Y.; Niu, Z.-J.; Zhou, X.-S., The binding sites of carboxylic acid group contacting to Cu electrode. Electrochemistry Communications 2015,59, 48-51.
7Li, D.-F.; Mao, J.-C.; Chen, D.-L.; Chen, F.; Ze-Wen, H.; Zhou, X.-Y.; Wang, Y.-H.; Zhou, X.-S.; Niu, Z.-J.; Maisonhaute, E., Single-molecule conductance with nitrile and amino contacts with Ag or Cu electrodes. Electrochimica Acta 2015,174, 340-344.
6.Chen, L.; Wang, Y. H.; He, B.; Nie, H.; Hu, R.; Huang, F.; Qin, A.; Zhou, X. S.; Zhao, Z.; Tang, B. Z., Multichannel conductance of folded single-molecule wires aided by through-space conjugation. Angewandte Chemie International Edition 2015,54 (14), 4231-5.
5.Wang, Y.-H.; Hong, Z.-W.; Sun, Y.-Y.; Li, D.-F.; Han, D.; Zheng, J.-F.; Niu, Z.-J.; Zhou, X.-S., Tunneling Decay Constant of Alkanedicarboxylic Acids: Different Dependence on the Metal Electrodes between Air and Electrochemistry. The Journal of Physical Chemistry C 2014,118 (32), 18756-18761.
4.Wang, Y.-H.; Li, D.-F.; Hong, Z.-W.; Liang, J.-H.; Han, D.; Zheng, J.-F.; Niu, Z.-J.; Mao, B.-W.; Zhou, X.-S., Conductance of alkyl-based molecules with one, two and three chains measured by electrochemical STM break junction. Electrochemistry Communications 2014,45, 83-86.
3.Wang, Y.-H.; Zhou, X.-Y.; Sun, Y.-Y.; Han, D.; Zheng, J.-F.; Niu, Z.-J.; Zhou, X.-S., Conductance measurement of carboxylic acids binding to palladium nanoclusters by electrochemical jump-to-contact STM break junction. Electrochimica Acta 2014,123, 205-210.
2.Zhou, X. Y.; Wang, Y. H.; Qi, H. M.; Zheng, J. F.; Niu, Z. J.; Zhou, X. S., Single-molecule conductance of dipyridines binding to Ag electrodes measured by electrochemical scanning tunneling microscopy break junction. Nanoscale Research Letters 2014,9 (1), 77.
1Peng, Z. L.; Sun, Y. Y.; Zhou, X. Y.; Wang, Y. H.; Zhou, X. S., The Influence of Conjugated Bond on Single Molecule Conductance of Carboxylic Acids Measured by Electrochemical Jump-To-Contact Scanning Tunneling Microscopy Break Junction. International Journal of Electrochemical Science 2013,8 (5), 6544-6552.